Kinetics and Mechanism of the Oxidation Reaction of Chlorine-Containing Hydrocarbons on a Vanadium Phosphorus Catalyst

Authors

  • Irada G. Melikova Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan https://orcid.org/0000-0002-7906-1556
  • Arif J. Efendi Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan
  • Manaf R. Manafov Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan https://orcid.org/0000-0002-9965-4850
  • Natavan F. Aykan Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan
  • Guseyn M. Faradjev Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan
  • Ceyran T. Rustamova Institute of Catalysis and Inorganic Chemistry named after acad. M. Nagiyev, Ministry of Science and Education of Republic of Azerbaijan, Baku, Azerbaijan
  • Nizami I. Shikhaliyev Azerbaijan Technical University, Ministry of Education of the Republic of Azerbaijan, Baku, Azerbaijan

DOI:

https://doi.org/10.31489/2959-0663/4-25-14

Keywords:

kinetic regularities, mechanism, vanadium-phosphorus catalyst, oxidation reactions, chlorinated hydrocarbons, product formation rate, fluidized bed, fixed catalyst bed, Bartlett’s criterion, chlorohydrocarbons

Abstract

The kinetic regularities of oxidation reactions of 1,2,4-trichlorobutene-2, 2,3,3-trichlorobutene-1, 1,2,3-trichlorobutene-2 and pentachlorobutene-1 on vanadium phosphorus catalyst exhibiting high activity and selectivity were studied. The presence of parallel-sequential pathways of XY oxidation with the formation of the main organochlorine compounds and deep oxidation products was established. Ii was shown that presence and location of the double bond and the number of chlorine atoms affected the direction of the oxidation reaction. The rate of XY consumption in a fixed catalyst bed exceeds that in a fluidized bed, although the rate of formation of the target product is higher in a fluidized bed. Hypotheses reflecting the possibility of a staged reaction mechanism taking into account the modification of the surface of the vanadium-phosphorus oxide system by the main and by-products of the oxidation reactions of chlorobutenes, as well as the competition of substances for active centers were investigated. Discrimination of these hypotheses was carried out on the basis of the Bartlett's criterion and Powell's method, and the mechanism that most fully explains the experimental results was selected. The calculated hardness values were obtained according to the proposed kinetic model by the Kutta-Meyerson and Runge-Kutta methods. A more detailed study of the mechanism of the oxidation reaction of chlorinated hydrocarbons will allow for effective control of its course and the achievement of selective oxidation of chlorinated hydrocarbons.

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Results of kinetic studies of the oxidation reaction of 2,3,3-TCB-1, dependence of the accumulation rate on the contact time. Confidence level Р = 95 %

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Published

2025-12-03

How to Cite

Melikova, I. G., Efendi, A. J., Manafov, M. R., Aykan, N. F., Faradjev, G. M., Rustamova, C. T., & Shikhaliyev, N. I. (2025). Kinetics and Mechanism of the Oxidation Reaction of Chlorine-Containing Hydrocarbons on a Vanadium Phosphorus Catalyst. EURASIAN JOURNAL OF CHEMISTRY. https://doi.org/10.31489/2959-0663/4-25-14

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Copyright (c) 2024 Irada G. Melikova, Arif J. Efendi, Manaf R. Manafov, Natavan F. Aykan, Guseyn M. Faradjev, Ceyran T. Rustamova, Nizami I. Shikhaliyev

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